Name the following compound : Answer. In the IUPAC system of nomenclature, functional groups are normally designated in one of two ways. Organic compound Word root Primary suffix IUPAC name CH 2 CH 2 CH 3 Prop ane Propane CH 2 = CH 2 Eth ene Ethane CH 3 C≡CH Prop yne Propyne CH 2 = CH – CH = CH 2 But dine Butadiene (b) Secondary suffix Secondary suffix gives the idea about nature of the functional group present in the compound. In IUPAC system the position of functional groups are indicated by arabic numerals i.e. Various Rules For Writing Names. Each such group (or substituent) is denoted by a secondary prefix. In the above example, one of the CN groups is considered as a substituent because it is not directly attached to the parent chain. Add your answer and earn points. IUPAC System (a) The full form of IUPAC system is International Union of Pure and Applied Chemistry. It is added after the primary suffix. This is common for the carbon-carbon double and triple bonds which have the respective suffixes - ene and - yne . Prefix (alphabetically) root word (alk) primary suffix (ene, yne) secondary suffix (main functional group) So IUPAC name of any organic compounds essentially consists of two or three parts. Thus, general format for IUPAC name of all compounds is: IUPAC name of all compounds contain word root and primary suffix but prefix and secondary suffix may not be present because all organic compounds must contain carbon chain and bond but substituent and functional group may not be present. (b) This system of nomenclature was first introduced in 1947 and was modified from time to time. Depending on the number of occurrences of the same functional group in a compound, the words like di, tri, tetra etc., are prefixed to the secondary suffix. General rules for IUPAC Nomenclature of organic compounds. Secondary suffix: Secondary suffix indicates the functional group present in the molecule. The presence of the function may be indicated by a characteristic suffix and a location number. Notice that the secondary suffix nitrile is used. 3) prefix No. Aldehyde (R-CHO)-CHO-al Alkanals 3. For example. Notice that the secondary suffix carbonitrile is used. Class Functional group Secondary suffix IUPAC name 1. The most important feature of this system is that any given molecular structure has only one IUPAC name and any given IUPAC name denotes only one molecular structure. The IUPAC name of any organic compound essentially consist of three parts ,i.e. (i) Root word (ii) Suffix (iii) Prefix (i) Root Words. ... but now aromatic compounds have their popular common name adopted by IUPAC. Alcohols (R-OH)-OH-ol Alkanols 2. Therefore, the IUPAC name of ethyl alcohol is “ethanol”. It … In the IUPAC system of nomenclature, groups are not considered as functional groups (which are indicated by secondary suffixes) but as substituents. It is saturated so the primary suffix should be “ane” but as there is a functional group (alcohol) “–OH” in the molecule, remove the “e” from the name of the molecule and add the secondary suffix “ol”. Prefix(es) + word root + primary suffix + secondary suffix. Ketones (RCOR') >C=O-one Alkanones 4. In order to have better understanding of various rules of nomenclature, let us discuss it in different parts as It is added after primary suffix. Arrangement of Prefixes, Word root and Suffixes: The prefixes, word root and suffixes are arranged as follows while writing the IUPAC name. Secondary suffix Secondary suffix is used to indicate the functional group in the organic compound secondary suffixes for various functional groups are given below. The terminal ‘e’ is dropped, if secondary suffix begins with a vowel (a, e, i, o, u, y) but it is retained if the secondary suffix begins with a consonant. 2) suffix. CH 3 –CH 2 –OH : Eth + an + ol : Ethanol. Sl. The basic unit is a series of root words which indicate linear or continuous chains of carbon atoms. dvs181202 dvs181202 i) Primary suffix: It is used to indicate the degree of saturation or unsaturation in the main chain. Some complicated namings. What are the primary and secondary suffixes as appiled to IUPAC nomenclature 1 See answer ameera43 is waiting for your help. 1) word root. Secondary Suffix: It is used to indicate the main functional group in the organic compound and is added immediately after the 1° suffix.